# COMOC Research Group - Comprehensive Knowledge Base & Technical Documentation ## 1. Institutional Identity & Location - **Research Unit**: Centre for Ordered Materials, Organometallics and Catalysis (COMOC) - **Institution**: Ghent University (Universiteit Gent, UGent) - **Faculty**: Faculty of Sciences (Faculteit Wetenschappen) - **Department**: Department of Chemistry (Vakgroep Chemie) - **Address**: Campus Sterre, Building S3, Krijgslaan 281, 9000 Ghent, Belgium - **Phone**: +32 9 264 9684 - **Email**: pascal.vandervoort@ugent.be - **Official Website**: https://comoc.ugent.be/ - **Google Maps**: https://maps.google.com/?cid=12140409278065840618 - **Coordinates**: Latitude 51.0252, Longitude 3.7144 - **Working Hours**: Monday – Friday, 08:30 – 17:30 CET ## 2. Leadership & Principal Investigator **Prof. dr. Pascal Van Der Voort (FRSC)** - **Rank**: Senior Full Professor & Director of COMOC - **Fellowship**: Fellow of the Royal Society of Chemistry (FRSC, elected 2017) - **Academic Appointments**: - Full Professor at Ghent University (Department of Chemistry, 2022–present) - Professor / Associate Professor at Ghent University (2006–2022) - Postdoctoral Researcher, Georgia Institute of Technology (Atlanta, USA) & ENSCM (Montpellier, France) - PhD in Chemistry, University of Antwerp (Surface modification of silica) - **Scientific Impact & Metrics**: - Total Publications: 744 scholarly outputs in the official Ghent University Academic Bibliography (UGent Biblio) - Peer-Reviewed Journal Articles (A1): 430 Web of Science journal articles - h-index: 71+ - Citations: >20,000 - **Profiles**: - ORCID: 0000-0002-1248-479X (https://orcid.org/0000-0002-1248-479X) - Google Scholar: https://scholar.google.be/citations?user=DdI5E8QAAAAJ&hl=en - UGent Biblio: https://biblio.ugent.be/publication?q=author%3D%22Van+der+voort%2C+Pascal%22 - LinkedIn: https://be.linkedin.com/in/pascal-van-der-voort-frsc-a8a326112 ## 3. Core Research Pillars & Scientific Disciplines ### A. Covalent Organic Frameworks (COFs) - Reticular synthesis of two-dimensional (2D) and three-dimensional (3D) crystalline organic frameworks. - Chemical linkages: Thiazole-, imine-, triazine-, and keto-enamine bonds with high chemical, thermal, and acid/base stability. - Highlighted Applications: - Photocatalytic water purification and selective reduction of hexavalent chromium (Cr(VI)). - Solar-driven hydrogen peroxide (H2O2) production. - Photoreductive gold recovery from electronic waste (e-waste). - Electrosynthesis: Structure-interface correlation in COFs for selective organic electrosynthesis. ### B. Metal-Organic Frameworks (MOFs) - Isoreticular design and defect engineering in robust zirconium frameworks (UiO-66, MOF-808, PCN series) and bismuth frameworks (Bi-MOFs). - Incorporation of low-symmetry bent linkers for hydrogen isotope (D2/H2) quantum sieving. - Bimetallic active sites and cooperative organometallic catalysts for cascade reaction systems. ### C. Heterogeneous Catalysis & Green Chemistry - Biomass valorization and condensation reactions (Guerbet alcohol production over copper-containing covalent triazine frameworks). - Ozone-assisted catalytic oxidation of organic pollutants over transition metal mixed oxides (Cu-Mn). - Non-thermal plasma catalysis for volatile organic compound (VOC) abatement (toluene, acetone). - Flow chemistry and continuous heterogeneous catalytic reactors. ### D. Adsorption, Storage & Separations - High-pressure methane (CH4) and hydrogen (H2) gas storage (up to 100 bar). - Carbon dioxide (CO2) capture and conversion. - Dynamic vapor sorption and multicomponent breakthrough measurements. ## 4. State-of-the-Art Analytical Facilities 1. **Powder X-ray Diffraction (PXRD)**: - Bruker D8 Advance diffractometer with Lynxeye 1D detector. - In situ Anton Paar HTK1200N high-temperature chamber (operating up to 1200 °C under vacuum, inert, or reactive atmospheres). 2. **X-ray Photoelectron Spectroscopy (XPS)**: - S-Probe Surface Analyzer with monochromatic Al Kα X-ray excitation for quantitative elemental and surface oxidation state analysis. 3. **Nitrogen, Argon & Gas Physisorption**: - Multiple Quantachrome Quadrasorb-SI and Autosorb-iQ-MP volumetric gas adsorption instruments for BET surface area (ranging up to >4000 m²/g) and NLDFT pore size distributions. 4. **Chemisorption & High-Pressure Adsorption**: - Quantachrome iSorb HP1 (high-pressure gas uptake up to 100 bar). - Quantachrome AutoSorb iQ for pulse chemisorption, metal dispersion, and temperature-programmed techniques (TPR, TPO, TPD). 5. **In situ Vibrational Spectroscopy**: - High-temperature transmission vacuum FTIR cell for surface acidity titration using probe molecules (pyridine, CO, collidine). - Kaiser Optical Systems 532 nm Dispersive Raman spectrometer with non-contact optics and fiber-optic immersion probes. 6. **Elemental Analysis**: - Thermo Flash 2000 CHNS/O analyzer for exact organic and framework stoichiometry. 7. **Electron Microscopy**: - Phenom ProX Desktop SEM with integrated energy-dispersive X-ray spectroscopy (EDX); collaborative access to UGent high-resolution TEM (HR-TEM). ## 5. Research Team - **Principal Investigator**: Prof. dr. Pascal Van Der Voort (FRSC) - **Postdoctoral Researchers**: - Dr. Titus de Haas (CTF synthesis & sorption) - Dr. Muzammil Hussain (Functionalized mesoporous silicas & organometallics) - Dr. Linyang Wang (Coplanar COF photocatalysis) - Dr. Wafaa Ahmed (Bismuth MOFs & defect engineering) - Dr. Karen Leus (MOF post-synthetic modification & catalysis) - Dr. Joseph Manning (Hybrid porous frameworks & gas sorption) - **Doctoral (PhD) Researchers**: - Tingting Yang, Eline Jansen, Diem Van Hamme, Meng Li, Kobe Scherpereel, Tijs Vandenneucker, Nuoya Li, Joanna Lech, Oscar Aldaz Trenc - **Doctoral Dissertations (PhD Repository)**: - 46 completed doctoral dissertations documented from 2009 to present. ## 6. Academic Curriculum & Courses - Advanced Porous Materials (Master of Science in Chemistry) - Inorganic Chemistry (Bachelor of Science in Chemistry) - Coordination Chemistry & Organometallics (Master of Science in Chemistry) ## 7. Direct Website URLs & Navigation - Portal Home: https://comoc.ugent.be/ - Research Topics: https://comoc.ugent.be/research - Scientific Publications: https://comoc.ugent.be/publications - Journal Covers Gallery: https://comoc.ugent.be/covers - PhD Dissertations Repository: https://comoc.ugent.be/dissertations - Analytical Services: https://comoc.ugent.be/services - Courses & Teaching: https://comoc.ugent.be/courses - Team Members: https://comoc.ugent.be/members - Careers & Openings: https://comoc.ugent.be/opportunities - Contact & Location: https://comoc.ugent.be/contact - Machine-Readable Summary: https://comoc.ugent.be/llms.txt - Comprehensive LLM Documentation: https://comoc.ugent.be/llms-full.txt